AA Aspects of Agriculture
AA1 Synopsis
A study of the contribution that chemists make towards ensuring a safe and sufficient food supply. Main topics:
• nutrient needs of crops;
• the fate of nutrients in the soil;
• redox chemistry of the nitrogen cycle;
• manufacture of nitrogenous fertilisers;
• designing pesticide molecules to perform specific functions;
• the fate of pesticides in the soil: degradation and accumulation.
AA2 Learning outcomes
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Candidates should be able to: |
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(a) |
discuss ways in which chemists can help improve food production, including: |
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(i) |
providing extra nutrients, |
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(ii) |
controlling soil pH, |
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(iii) |
controlling pests; |
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(b) |
recall the qualitative effect of temperature on the rate constant of a reaction;
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(c) |
discuss the redox reactions involved in the interconversion of the following species in the |
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nitrogen cycle: |
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(i) |
nitrogen gas, |
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(ii) |
nitrate(V) ion, |
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(iii) |
nitrate(III) ion, |
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(iv) |
ammonium ion, |
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(v) |
dinitrogen oxide(N2O), nitrogen monoxide(NO), nitrogen dioxide(NO2); |
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(d) |
describe in outline the manufacture of ammonia in the Haber Process, giving essential |
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conditions; |
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(e) |
Use given data to evaluate the most economical operating conditions for an indusrial process such as the Haber process , using principles of equilibrium and rates of reaction. |
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(f) |
write an expression for the equilibrium constant, Kp, for reactions involving gases (in terms of partial pressures)
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(g) |
Use values of Kp together with given data on partial pressures to carry out simple calculations concerning the composition of equilibrium mixtures. |
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(h) |
Describe and explain, in terms of structure and bonding the trends in reactions of the elements and properties of compounds across a period, including: |
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(i) |
the reactions of the elements with oxygen, chlorine and water, |
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(ii) |
the acid-base character of oxides, |
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(iii) |
the behaviour of chlorides towards water; |
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(i) |
recall that there is a relationship between the structure and bonding of a substance and its |
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properties, and relate the properties of substances to their structure and bonding; |
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(j) |
interpret given data in terms of the structure and bonding of a substance; |
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(k) |
describe and explain the partition equilibrium that occurs when a solute is distributed |
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between two immiscible solvents; |
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(l) |
explain the role of chemistry in the design of pesticides that combine maximum efficacy with minimum environmental damage. |
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